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ادامه مطلب1. Introduction. Ettringite Ca 6 Al 2 (SO 4) 3 (OH) 12 ⋅ 26H 2 O(C 6 A S ¯ 3 H 32 in cement chemistry notation) is one of the prominent compounds formed during cement hydration. Ettringite crystal structure has columns which run parallel to the c or needle axis [1].Its unit-cell is hexagonal, space group P31c, with a = 11.167 Å and c = 21.354 Å …
ادامه مطلبEttringite contains 26 water molecules and can resist expansive increases in volume when exposed to hydration, thereby leading to a significant heave effect, swelling, and decline in compressive strength . Many types of equipment and tests have been utilized to determine the negative impact of sulfate on soil stabilization. The most …
ادامه مطلبThe most common equipment and tests are unconfined compressive strength (UCS) tests used to reveal the influence of ettringite on the strength of soil …
ادامه مطلبEttringite ETTRINGITE (Ca 6[Al(OH) 6 l 2 (S0 4 ) 3.26H 20) occurs as a natural mineral, and is technically important as a hydra ... means of a Digital Equipment PDPS-S computer. Some
ادامه مطلبThis paper is the first one of the two papers dealing with the construction test. UHPFRC mix used in the construction test is called AFt-UHPFRC because it is characterised by its matrix densified by controlled ettringite (AFt) formation. UHPFRC was produced in a batching plant built in a testing field of that production capacity is 3.0 m 3 …
ادامه مطلبGrowth process of ettringite crystals was studied by a step-by-step crystallization method. Ettringite crystals were first synthesized with the previously …
ادامه مطلبAs to ettringite methods, two formulations were selected to perform sulfate removal in seawater. One formulation is NaAlO 2 and CaO, and the other is polyaluminum chloride (PAC) with AlCl 3 and CaO. The results showed the formulation of PAC/AlCl 3 /CaO could only reduce 50% of sulfate and resulted in an increase of calcium concentration. …
ادامه مطلبIn order to have a better understanding of the role played by SO 4 2− and Ca 2+ ions and ettringite formation on the rheological behavior of cementing systems …
ادامه مطلبThe formation of ettringite in compressed expanding cement paste at w/c 0.25 and compressed at 50, 200 and 500 kg/cm 2 have shown that there is not much influence of …
ادامه مطلبSP generally affects hydration by the reduced formation of calcium hydroxide (Ca(OH) 2) and ettringite in the initial ages of curing, which can be identified through XRD [42, 43]. The XRD analysis was conducted with a powder diffractometer. In this equipment, the Cu K α (λ = 1.5418
ادامه مطلب1. Introduction. Portland cement is the most consumed manufactured material globally, with an average production of 4.6 Gt per year. Although its invention dates back approximately 200 years (patent GB 5022 granted in 1824), we still do not fully understand its reaction mechanisms – the so-called hydration reactions [1].Therefore, in addition to …
ادامه مطلبThe search for new materials to replace Portland cement (PC) has increased due to the high release of carbon dioxide (CO2) and the exploration of raw materials for its production. In this case, supersulfated cement (SSC) appears as an option. SSC consists of up to 90% blast furnace slag and small percentages of calcium sulfate and alkaline …
ادامه مطلبThe cement industry is an energy-intensive industry, and improving the energy efficiency of cement has become necessary to reduce its carbon footprint and to compete in the global market. Clinker production consumes more than 90% of the total energy used in the cement industry. Therefore, a reduction in the burning temperature of the cement clinker …
ادامه مطلبIt is well known that cement production is not neutral for natural environment among others due to high CO2 emission. Different strategies of mitigation of negative environmental impact of its production are developed. One of the ways is utilization of supplementary cementitious materials (SCMs) in the manufacture of cement and …
ادامه مطلبEttringite is either colorless or white in color. It is transparent in appearance and non-magnetic. The mineral is non-fluorescent with white streak, perfect cleavage and vitreous luster. It forms needle-like crystals. The hardness of ettringite ranges from 2 to 2.5, and its density is 1.8 g/cm 3.
ادامه مطلبEttringite was successfully synthesized in the laboratory by simulating conditions close to those in chemically treated sulfate-bearing soils. ... for providing SEM and XRD equipment access to the present research. ... Burkart, B., Goss, C. G., and Kern, P. J. (1999). "The role of gypsum in production of sulfate-induced deformation of lime ...
ادامه مطلبThis study investigates the development of solidification technology, based on the formation of ettringite, for fluorine-contaminated bassanite using waste and recycled materials. Recycled bassanite is mixed with coal ash, blast furnace slag and furnace cement type B in varying proportions to obtain the optimal ettringite production, based on the …
ادامه مطلبAfter this initial burst of precipitation, the growth of ettringite crystals occurs at a near-constant, slow rate for the ensuing hours until SO 4 2− ions in the solutions are depleted 36,38,39 ...
ادامه مطلبReceived 31 May 2016. Revised 29 Jul 2016. Accepted 16 Aug 2016. Published 07 Sept 2016. Abstract. In order to save limited natural resources by utilising industrial by …
ادامه مطلبOne of the main challenges in industrial wastewater treatment and recovery is the removal of sulfate, which usually coexists with Ca 2+ and Mg 2+.The effect of Mg 2+ on sulfate removal by ettringite precipitation was investigated, and the process was optimized in the absence and presence of Mg 2+.In the absence of Mg 2+, the optimum conditions …
ادامه مطلبDuring the production of cement, the operation of equipment requires a large amount of electricity, mainly including clinker production and cement grinding (Teo et al., 2010). The generation of electricity by using fossil fuels emits a lot of CO 2, which is regarded as indirect CO 2 emissions.
ادامه مطلبOperating costs for near-complete sulfate removal using the process, which has been demonstrated successfully for many industrial waters, are estimated at $3 to $6 per 1000 gallons treated. Hydrometrics, Inc., 2727 Airport Road, Helena, MT 59601. Tel: 406-443-4150; Fax: 406-443-0760. Many industrial wastewaters, particularly those associated ...
ادامه مطلبThe production process for MSWI FA-derived lightweight aggregates is shown in Fig. 7 (Colangelo et al., 2015, Quina et al., 2018, Tang et al., 2017). Sintering as the principal thermal treatment was applied to recycle the MSWI FA into lightweight aggregates for the purpose of immobilising PTEs, reducing the volume of the MSWI FA, …
ادامه مطلبThere are several theories about expansion mechanism of self-expanding concrete: (1) volume increase in gel state expansive ingredients by water absorption, i.e., swelling theory [5, 6]; (2) spreading out of surroundings by crystal growth of crystalline expansive ingredients, i.e., crystal growth theory [7,8,9,10]; and (3) forming coexisting …
ادامه مطلبThe ability of ettringite to immobilize ions is based on the mineral being an effective ion exchanger (Chen et al., 2009).Calcium and aluminum cations (Ca 2+ and Al 2+, respectively) and sulfate anions (SO 4 2−) can be substituted in the matrix with a wide variety of cations and oxyanions of similar ionic charge (Fig. 1) (Chen et al., …
ادامه مطلبAll of the phases in the production of Calcium sulfoaluminate-belite cement, which has ettringite as an intermediate in the production process, are stable at a temperature of approximately 1250 C, which is about 200 C lower than the temperature used for Portland cement production, and thus has lower energy consumption and lower …
ادامه مطلبThe development of ettringite and gypsum was the primary cause of the growth (Chotetanorm et al. 2013). The FA/GGBFS (ground granulated blast furnace slag) concrete expanded by 0.04% and lost 33% of its mechanical resistance after 360 days in MgSO4, compared to 0.08 and 48%, respectively, for similarly treated OPC concretes.
ادامه مطلبThe production of valuable cementitious materials from fluidized bed combustion ... This is due to the uncontrolled production of ettringite (Ca 6 Al 2 (SO 4) 3 (OH) 12•26 H 2 O), the primary cementitious mineral, and the delayed hydration of "dead burned" or beta-form anhydrous calcium sulfate (β-CaSO 4, anhydrite). This work is part of ...
ادامه مطلب